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A redox-active radical as an effective nanoelectronic component: stability and electrochemical tunnelling spectroscopy in ionic liquids.

Rudnev, A V*; Franco, C*; Crivillers, N*; Seber, G*; Droghetti, A*; Rungger, I; Pobelov, I V*; Veciana, J*; Mas-Torrent, M*; Rovira, C* (2016) A redox-active radical as an effective nanoelectronic component: stability and electrochemical tunnelling spectroscopy in ionic liquids. Phys. Chem. Chem. Phys., 18 (40). pp. 27733-27737.

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Abstract

A redox-active persistent polychlorotriphenylmethyl (PTM) radical chemically linked to gold exhibits stable electrochemical activity in ionic liquid. Electrochemical tunnelling spectroscopy in this medium demonstrates that the PTM radical shows a highly effective redox-mediated current enhancement, demonstrating its applicability as an active nanoelectronic component.

Item Type: Article
Keywords: surface chemistry, molecules on surfaces, charge transfer processes
Subjects: Advanced Materials
Advanced Materials > Materials Modelling
Identification number/DOI: 10.1039/c6cp05658j
Last Modified: 02 Feb 2018 13:13
URI: http://eprintspublications.npl.co.uk/id/eprint/7280

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